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Chemical vs. Biological Weapons

Introduction : Chemical weapons
Introduction : Biological Weapons
The Lethal Factor
Improvised Manufacture
Deployment Techniques
Protection Against
Examples of CW's : Sarin
Examples of CW's : VX Gas
Examples of BW's : Anthrax
Examples of BW's : Botulin Toxin

Introduction : Chemical Weapons
Chemical weapons known as Nerve Agents were discovered accidentally by German Scientist Gerhard Schrader in 1936. Shcrader was working on developing a chemical to fight insects (insecticides), on his success he sprayed a dilute solution of what is now known as the Tabun Nerve Agent on a group of insects. However, a short time later he developed side effects related to vision and breathing that lasted three weeks. And so the discovery. Although Chemical Agents such as chlorine and phosgene gas were first used during the first World War in trench warfare their lethality did not compare to that of nerve agents. Nerve Agents work by unbalancing the Nervous system and thus paralysing the subject's muscles and arresting the respiratory (Breathing) system causing death.

Introduction : Biological Weapons
Biological Weapons are a lot more difficult to trace in history. During the ancient siege of a city a disease infected carcas would be thrown into the city to cause the infection to spread throughout the population. Due to the cold war research into BW's was intensified leading to the further development of toxins generated by bacteria (such as the botulin toxin). Biological Agents work by several ways, either by infecting the human body with disease or unbalancing the body's system as with toxins.

The Lethal Factor
Which is more lethal, BW or CW ? This question cannot really apply to toxicity as different factors apply. Chemical Weapons have the property of killing instantly with a lethal dose possible as 10 milligrams, that's one hundredth the weight of a gram. The lethal dose of CW would usually cause a paralysis of muscles and the stopping of breathing. However, Biological Weapons do not kill instantly, a very small amount of bacteria can infect and kill 100% of people exposed in three to seven days (such as anthrax). Certain BW's can have the added trait of being contageous (unlike CW's), further multiplying their lethality factor. In a weight to weight ratio related to exposure by inhalation CW's are more lethal than BW's. BW's can be further modified by genetic engineering, it is certainly possible that a Biological Weapon targeting an ethnic group is being or has been developed by the military. There are not many documented incidents of the use of such military weaponry against a civillian population, such few examples being the Tokyo subway attack and an incident were a U.S. Ship leaked mustard gas in an Italian harbor killing upto 1000 people during the second world war.

Improvised Manufacture
There has been a lot of controversy and fear around the idea of terrorists obtaining this kind of technology and causing havoc in a major city. The Anthrax letters which were posted to targets in the U.S. are an example of the use of BW's by terrorists. It should be noted that there are severe complications in the improvised manufacture of BW's. Military grade BW's are usually in the form of a very fine powder for the purpose of easy dispersal over the target zone. An equivalent improvisation by an individual is nearly impossible as a lot of equipment and expertise is needed to achieve the powdered form. It is very easy and cheap to achieve a sludged consistency, an example would be to take samples of anthrax from an infected farm animal and use a biological culture medium such as blood "agar" to allow the anthrax bacteria to multiply resulting in a large supply of anthrax sludge. This sludge cannot be dispersed effectively over a large area so this technique is quite useless. Chemical Weapons which are much more expensive to improvise, can be manufactured by a college level Chemistry graduate. The procedure would require chemicals and equipment available in Chemical supply companies. An example is the Tokyo Subway attacks where an unconcentrated form of Sarin Nerve Agent was used to cause havok, had the Sarin been military grade the consequences would have been disastrous. The procedures and research to improvise CW's are readily available to the public. Several years ago controversial books on the subject of CW and BW improvisation were readily available through the internet, but today these have been taken 'off the shelves' in the interest of public safety. Gerhard Shrader's research into the production of Sarin Nerve Agent has been declassified after world war 2 and is available to anyone through conventional library sources.

Deployment Techniques
The very important aspect of CW and BW is how delivery to the target is handled. To contrast effective and non effective techniques the Tokyo Subway incident can be used. In this case a bottle of a crude form of sarin was opened and left to evaporate naturally with severe effects on the commuters. An effective technique would involve the wide dispersal of Sarin at an altitude above a city center. A small aeroplane can be used to achieve this with horrific results to the population below. A spray nozzle or 'drop box' could be used for either CW or BW assuming they are of the correct consistency. Another way is to attach a low temperature explosive device to a container of BW/CW and set it to explode a certain altitude above a crowded area using an electronic altemeter detonator. In such a dispersion scenario the Boiling Point of the CW is important as it defines the way the chemical disperses and reacts to high temperatures. As an example if volatile Sarin is exploded above the target on a very hot day a lot of it would evaporate needlessly, further to that the area would only be contaminated for a short time as the sarin would all evaporate eventually.

A very simple problem exists with deployment. The substances used are so toxic that physical contact can cause death to the personnel handling the weapons. Conventional techniques have artillery shells filled with CW or BW. This is usually overcome by filling the shells with the substance seconds before the shell is inserted and launched by artillery, therefore avoiding the hazardous transportation of CW or BW shells by conventional soldiers. In the case of CW a special alternative exists to this in the form of Binary Weapons. Instead of storing a CW two reactants are stored seperately and mixed en route to the target by the rotating artillery shell after just being dispatched by the cannon.

Ways to protect against
Chemical weapons can gain entry to the body through contact, inhalation or ingestion. Similarly Biological Weapons designed for effective dispersion. To protect against such weaponry the body will have to be totally isolated from the substance and a filter established for breathing. This is what an NBC suit does (Nuclear Biological Chemical). These suits can be reused repeatedly or come in the disposable form. In addition there is always the chance of exposure even with a suit so protective medication is required; For CW an injection of Atropine along with an inhibitor related to the nervous system is required (such as Contrathion), in combination these two chemicals work against the loss of balance in the nervous system caused by the CW. BW's are more complicated as a vaccine is required to protect against the effect of the BW disease or the use of a powerful antibiotic to help fight the infection (such as DoxyCycline). Coupled together the NBC suits, medication and early warning devices help protect against the threat of CW and BW.

Examples of CW's : Sarin
Sarin, chemical name Isopropyl Methyl Phosphonoflouridate can be synthesized in a good chemical laboratory, it is a thin oily liquid clear to amber in color and odourless. The fatal inhalation dosage is 10 milligrams. Death can occur to the target in 1 to 10 minutes with indications of dim vision, runny nose, tightness in the chest, nausea, diarrhea, coma and respiratory failure. Sarin used to be the standard nerve agent used by the United States. It was invented by Gerhard Schrader during World War 2. The main trouble with using Sarin is that it is very volatile so tends to evaporate from the target area before its full effect can take place.

Examples of CW's : VX Gas.
VX, chemical name S-(2-DiisopropylAminoEthyl)-0-EthylMethylphonothiolate can be synthesized in a good chemical laboratory, it is a heavy oily liquid like motor oil clear in color and odourless. The fatal inhalation dosage is 10 milligrams, Death occurs to the target in 10 minutes with indications of dim vision, runny nose, tightness of chest, sweating, muscular twitching, nausea, vomiting, weakness and coma. VX was discovered out of insecticide research done in Britain. VX has a high vapor pressure in contrast with Sarin therefore it is very persistent on the target (it will not evaporate easily). This factor gives VX a very lethal skin contact dosage of 2 milligrams as compared to Sarin's 10 milligrams.

Examples of BW's : Anthrax
Anthrax (Bacillus Anthracis) was discovered in the mid 19th century. It is thought to be behind the death of many people in medieval europe and ancient Egypt. The Japanese first looked into the use of anthrax as a military weapon in 1930. It is considered as the perfect biological weapon because of the fact that it is extremely persistent. It will contaminate the area of a natural target for years before it can be cleaned up. Once exposed it is fatal to 100% of all exposures and will lead to death in 3 to 7 days. Although it is not contageous several different types exist; Anthrax can be lethal when inhaled but other types exist that are activated on contact with the skin. Anthrax has received a lot of coverage in the news recently due to the Anthrax Letters which were posted to the U.S. after the September 11 incident.

Examples of BW's : Botulin Toxin
Botulin is an exception to the rule of Biological Weapons. The Bacteria Clostridia Botulinum produces the Botulin Toxin as a by product. The fatal dose of the Botulin Toxin is 1 microgram, that's one millionth of a gram in weight. Theoretically speaking, 1 gram of this toxin is enough to kill 1 million people making it the second best poison in the world. A lot of coverage of this weapon has been attributed to food poisoning, therefore it is not expected to be used as a weapon. Small quantities of Botulin Toxin can be created rather easily with basic Biological principles.

 

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